PRODUCTION OF FURANS FROM PULP SHEET OVER SULFATED SOLID ACID CATALYSTS

Hongdan Zhang, Shubin Wu, Jun Zhang, Bo Li

Abstract


Furans are high value-added biomass-derived chemicals that can be used to replace petrochemicals. In this study, sulfated solid acid catalysts were prepared by precipitation and impregnation and were used for the conversion of a cellulosic pulp sheet into furans. The physicochemical properties of the prepared sulfated solid acid with different calcination temperatures and different mol ratios of Ti-Al were characterized using XRD, elemental analysis, TG, and NH3-TPD. Furthermore, the effects of various processing parameters such as temperature, time, and catalyst dosage on the reaction performance were studied. The combined yield of 5-hydroxymethyl-furfural and furfural reached 8.9% and 4.5% of pulp sheet mass with a 5% dosage of SO42-/TiO2-Al2O3 catalyst at 220 °C for 30 min. The activity for recovered catalyst was also investigated in this study.

Keywords


Pulp sheet; Sulfated solid acid; 5-Hydroxymethylfurfural; Furfural

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