Effects of Ageing on the Color and Surface Chemistry of Paulownia Wood (P. elongata) from Fast Growing Crops

Xin You Liu, Maria Cristina Timar, Anca Maria Varodi, Song Lin Yi

Abstract


The behavior of paulownia wood (Paulownia elongata) was investigated using three different ageing tests: simulated natural ageing under the influence of light under indoor conditions, temperature-induced ageing in the dark, and UV-induced ageing. Ageing effects were evaluated by color measurements in the CIE Lab system. Simulated natural ageing of wood in indoor conditions (6 months) and UV-accelerated ageing (72 h) are complex and dynamic processes, which resulted mostly in yellowing of the samples due to photo-degradation. Temperature-induced ageing (288 h at 100 C) resulted mostly in a rapid and visible darkening of the paulownia wood. Comparative in-time evolution of color changes during accelerated UV ageing testing and simulated natural ageing testing under indoor conditions allowed the estimation of an acceleration index of about 50X. Fourier transform infrared spectroscopy (FTIR) was used to examine specific chemistry changes occurring during these ageing tests. UV light from natural or artificial sources caused primarily lignin degradation followed by oxidative processes leading to carbonyl-containing chromophores. Temperature-induced partial degradation of hemicelluloses and oxidative processes resulted in the formation of chromophores containing mostly conjugated carbonyl groups. This research highlighted that paulownia wood (P. elongata) is quite sensitive to ageing under the action of light and temperature, which cause notable color and surface chemistry changes.

Keywords


Paulownia; Artificial ageing; Natural ageing; Color change; FTIR

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Welcome to BioResources! This online, peer-reviewed journal is devoted to the science and engineering of biomaterials and chemicals from lignocellulosic sources for new end uses and new capabilities. The editors of BioResources would be very happy to assist you during the process of submitting or reviewing articles. Please note that logging in is required in order to submit or review articles. Martin A. Hubbe, (919) 513-3022, hubbe@ncsu.edu; Lucian A. Lucia, (919) 515-7707, lucian.lucia@gmail.com URLs: bioresourcesjournal.com; http://ncsu.edu/bioresources ISSN: 1930-2126