Regulation of Superoxide Anion Radicals in Bagasse Alkali-Oxygen Pulping to Enhance Delignification Selectively

Xing Liang, Bing Sun, Yuxin Liu, Bao Zhang, Yingzhen Shan, Xueping Song, Shuangxi Nie


Alkali-oxygen pulping has received increasing attention as an environmentally compatible pulping process; however, the resulting pulp has low yield and properties due to carbohydrate degradation. In this work, the effect of regulating superoxide anion radicals (O2-•) on delignification selectivity in alkali-oxygen pulping was investigated. The pulp was characterized by Brunauer-Emmett-Teller (BET) analysis, scanning electron microscope (SEM), and X-ray diffraction (XRD). Lignin removal was improved by the regulation of O2-• in the 1,2,3-trihydroxybenzene auto-oxidation system with addition of sodium 2-anthraquinonesulfonate, especially for the pulp from cooking time 120 min. The degree and selectivity of delignification were improved with alkali-oxygen pulping when sodium 2-anthraquinonesulfonate was added to facilitate the generation of superoxide anion radicals. The results showed that the increased fiber liberation was beneficial for the accessibility of O2-• to lignin, which would improve the removal of lignin with negligible damage on cellulose, especially with regards to crystal area.


Superoxide anion radicals; Sodium 2-anthraquinonesulfonate; Alkali-oxygen pulping; Selectivity; Bagasse

Full Text: PDF

Welcome to BioResources! This online, peer-reviewed journal is devoted to the science and engineering of biomaterials and chemicals from lignocellulosic sources for new end uses and new capabilities. The editors of BioResources would be very happy to assist you during the process of submitting or reviewing articles. Please note that logging in is required in order to submit or review articles. Martin A. Hubbe, (919) 513-3022,; Lucian A. Lucia, (919) 515-7707, URLs:; ISSN: 1930-2126