The Effect of Treating Pine Regular Kraft Pulp with Peracetic Acid before O2-Delignification on the Consumption of ClO2 in D0ED1 Bleaching

Abstract

Effects of pre-treating pine kraft pulp kappa number 31.5 with peracetic acid (Paa) (0.33% and 0.66% as active oxygen based on oven-dried pulp) before O₂-delignification were studied relative to the consumption of chlorine dioxide in a subsequent Elemental Chlorine Free (ECF) bleaching process. The study showed that such pre-treatment is an effective way to extend the delignification of the pine pulp and to reduce the consumption of chlorine dioxide required to bleach the pulp to a brightness of 87%. The reduction in chlorine dioxide required to bleach the pine pulp depended on the amount of Paa used for pre-treatment. Furthermore, the research showed that decreasing the kappa number of the pine pulp to approximately 7.5 units (with Paa pre-treatment and lengthening of O₂-delignification process) caused an over-proportional reduction (by approximately 62.5%) in chlorine dioxide consumption to bleach the pulp to 87% brightness.