Thermoplastic Sugar Palm Starch Reinforced Graphene Nanoplatelets for Sustainable Biocomposite Films

Authors

  • Noor Fadhilah Rahmat Research Center for Sustainable Process Technology (CESPRO), Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia; Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia; Department of Physics, Centre for Defence Foundation Studies, Universiti Pertahanan Nasional Malaysia, 57000 Kuala Lumpur, Malaysia
  • Mohd Shaiful Sajab Research Center for Sustainable Process Technology (CESPRO), Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia; Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia
  • Atiqah Mohd Afdzaluddin Institute of Microengineering and Nanoelectronics, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia
  • Ding Gongtao Key Laboratory of Biotechnology and Bioengineering of State Ethnic Affairs Commission, Biomedical Research Center, Northwest Minzu University, Lanzhou 730030, PR China
  • Chin Hua Chia Materials Science Program, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, Bangi, Malaysia

Keywords:

Biocomposite, Graphene, Sustainable packaging, Starch

Abstract

Graphene nanoplatelets (GNP) were incorporated into thermoplastic starch (TPS) films, and effects on water absorption and mechanical properties were investigated. GNP inclusion formed a barrier that significantly reduced water absorption, resulting in denser TPS/GNP films. Fourier-transform infrared spectroscopy (FTIR) revealed changes in chemical interactions, and FESEM analysis showed improved GNP dispersion at this concentration. Water contact angle results indicated increased hydrophobicity with higher GNP content. Positive influences on mechanical properties, such as tensile strength and Young's modulus, were observed at 12 wt% GNP, but excessive GNP content caused agglomeration and reduced ductility. The study results highlight the potential of GNP-reinforced TPS films for improved water resistance and mechanical properties, emphasizing the need for careful optimization in future research.

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Published

2024-01-16

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Section

Research Article or Brief Communication