Properties of Poplar Veneer Modified by Acid Red 3R Dye in Combination with Ammonium Dihydrogen Phosphate

Authors

  • Xin Shi School of Materials and Chemistry, Anhui Agricultural University, Hefei 230036, Anhui, China
  • Hao Shen School of Materials and Chemistry, Anhui Agricultural University, Hefei 230036, Anhui, China
  • Shenglei Qin School of Materials and Chemistry, Anhui Agricultural University, Hefei 230036, Anhui, China
  • Yangguang Liu School of Materials and Chemistry, Anhui Agricultural University, Hefei 230036, Anhui, China
  • Xiaoshuang Shen School of Materials and Chemistry, Anhui Agricultural University, Hefei 230036, Anhui, China; Forest Material Improvement and Efficient Utilization of The National Forestry and Grassland Administration Key Laboratory, Hefei 230036, Anhui, China
  • Demiao Chu School of Materials and Chemistry, Anhui Agricultural University, Hefei 230036, Anhui, China; Forest Material Improvement and Efficient Utilization of The National Forestry and Grassland Administration Key Laboratory, Hefei 230036, Anhui, China
  • Shengquan Liu School of Materials and Chemistry, Anhui Agricultural University, Hefei 230036, Anhui, China; Forest Material Improvement and Efficient Utilization of The National Forestry and Grassland Administration Key Laboratory, Hefei 230036, Anhui, China

Keywords:

Poplar wood, Ammonium dihydrogen phosphate, Acid dyes, Dyed and flame retardant wood, Dye-uptake, Color difference, Oxygen index

Abstract

Ammonium dihydrogen phosphate (ADP) is a nitrogen-phosphorus-based inorganic flame retardant that is environmentally friendly and non-toxic. Wood treated with ADP has enhanced thermal stability and flame retardancy. Compounding ADP with Acid Red 3R dye further improves the decorative effect of the wood on the basis of excellent flame retardancy, resulting in a kind of dyeing and flame retardant multifunctionalized wood. Single-factor tests were designed to investigate the effects of flame retardant concentration, dye concentration, temperature, and time on three evaluation indexes: dye-uptake, color difference, and oxygen index, respectively. Through SEM and FTIR analysis, it was found that after the wood was simultaneously treated with flame retardant and dye, the two additives were aggregated in the grain pores of the cell wall by a simple physical combination. They did not undergo a chemical reaction. TG analysis showed that fire-retardant dyed wood had good thermal stability, which can delay the thermal degradation of wood and increase the residual charcoal rate of wood. XRD showed that the crystallinity of fire-retardant dyed wood increased compared to untreated wood. Through cone calorimetric test, it is found that flame retardant dyed veneer had excellent flame retardancy.

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Published

2024-04-16 — Updated on 2024-04-18

Issue

Vol. 19 No. 2 (2024)

Section

Research Article or Brief Communication